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Electrocatalytic properties of hydroxyapatite thin films electrodeposited on stainless steel substrates

Ahmed Chennah, Yassine Naciri, Hassan Ait Ahsaine, Aziz Taoufyq, Bahcine Bakiz, Lahcen Bazzi, Frédéric Guinneton, Jean-Raymond Gavarri, Abdeljalil Benlhachemi

Abstract


In this work, we have investigated the structural, microstructural, and electrocatalytic properties of hydroxyapatite (HAp) thin films. The HAp films were electrodeposited on stainless-steel (SS) substrates by chronopotentiometry mode from an electrolytic solution. The HAp films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray energy dispersion spectroscopy (EDS). The electrodeposition and electrochemical processes of the hydroxyapatite (HAp) phase were studied by cyclic voltammetry. This HAp/SS system acting as an anode was used for the first time to electrodegrade Rhodamine B (RhB) in aqueous solutions. To follow the degradation kinetics, we used UV-visible spectroscopy. Several parameters such as the current density and the initial concentration of electrolytic solution were determined to optimize the electrodegradation of RhB. The decrease of RhB concentration followed pseudo-first order kinetics law. The rate of RhB degradation in presence of HAp/SS electrode can reach interesting high performance, depending on the electrocatalysis experimental conditions.


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References


- D.F. Williams, On the mechanisms of biocompatibility, Biomaterials, 2008, 29, 2941–2953.

- W. Cao, L.L. Hench, Bioactive materials, Ceram. Int., 1996, 22, 493–507.

- L.L. Hench, Bioactive materials: The potential for tissue regeneration, J. Biomed. Mater. Res. 1998, 41, 511–518.

- S. Jegannathan, T.S.N.S. Narayanan, K. Ravichandran, S. Rajeswari, Formation of zinc phosphate coating by anodic electrochemical treatment, Surf. Coatings Technol., 2006, 200, 6014–6021.

- L. Kőrösi, I. Dékány, Preparation and investigation of structural and photocatalytic properties of phosphate modified titanium dioxide, Colloids Surfaces A Physicochem. Eng. Asp., 2006, 280, 146–154.

- J. Ryu, K. Y. Kim, B. D. Hahn, J. J. Choi, W. H. Yoon, B. K. Lee, D. S. Park, C. Park, Photocatalytic nanocomposite thin films of TiO2-β-calcium phosphate by aerosol-deposition, Catal. Commun., 2009, 10, 596–599.

- B. León, Pulsed Laser Deposition of Thin Calcium Phosphate Coatings: Thin Calcium Phosphate Coatings Medical Implants; ed. by JA Jansen, B Leon, Springer: New York, 2009, 101-155.

- U.M. Gross and D. Lassner, In Vitro and In Vivo Evaluation of Thin Calcium Phosphate Coatings: In Thin Calcium Phosphate Coatings Medical Implants: ed. by JA Jansen, B Leon, Springer: New York, 2009, 67-99.

- H. Benhayoune, R. Drevet, J. Fauré, S. Potiron, T. Gloriant, H. Oudadesse, D. Laurent-Maquin, Elaboration of Monophasic and Biphasic Calcium Phosphate Coatings on Ti6Al4V Substrate by Pulsed Electrodeposition Current, Adv. Eng. Mater., 2010, 12, B192-B199.

- R. Chakraborty, S. Sengupta, P. Saha, K. Das, S. Das, Synthesis of calcium hydrogen phosphate and hydroxyapatite coating on {SS316} substrate through pulsed electro-deposition, Mater. Sci. Eng. C, 2016, 69, 875–883.

- N. Ben Jaber, R. Drevet, J. Fauré, C. Demangel, S. Potiron, A. Tara, A. Ben Cheikh Larbi, H. Benhayoune, A New Process for the Thermal Treatment of Calcium Phosphate Coatings Electrodeposited on Ti6Al4V Substrate, Adv. Eng. Mater., 2015, 17, 1608–1615

- P. Arunachalam, M.N. Shaddad, A.S. Alamoudi, M.A. Ghanem, A.M. Al-Mayouf, Microwave-Assisted Synthesis of Co3(PO4)2 Nanospheres for Electrocatalytic Oxidation of Methanol in Alkaline Media, Catalysts, 2017, 7, 119.

- T. Liu, Y. Liang, Q. Liu, X. Sun, Y. He, A.M. Asiri, Electrodeposition of cobalt-sulfide nanosheets film as an efficient electrocatalyst for oxygen evolution reaction, Electrochem. Commun., 2015, 60, 92-96.

- Q. Lu, K. Chen, W. Pan, X. Wu, K. Lu, Z. Xu, R. Liu, Room Temperature Electrodeposition of Ag3PO4 Films, J. Electrochem. Soc., 2016, 163, D206–D211.

- M. Lefèvre, E. Proietti, F. Jaouen, J. P. Dodelet, Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells, Science, 2009, 324, 71-74.

- G. C. Luque, J. L. Fernández, Electrocatalysis of oxygen reduction at electrodeposited molybdenum phosphate-based films, J. Power Sources, 2012, 203, 57-64.

- R. Murugavel, A. Choudhury, M.G. Walawalkar, R. Pothiraja, C.N.R. Rao, Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications, Chem. Rev., 2008, 108, 3549-3655.

- K. Baďurová, O. Monfort, L. Satrapinskyy, E. Dworniczek, G. Gościniak, G. Plesch, Photocatalytic activity of Ag3PO4 and some of its composites under non-filtered and UV-filtered solar-like radiation, Ceram. Int., 2017, 43, 3706-3712.

- X. Song, R. Li, M. Xiang, S. Hong, K. Yao, Y. Huang, Morphology and photodegradation performance of Ag3PO4 prepared by (NH4)3PO4, (NH4)2HPO4 and NH4H2PO4, Ceram. Int., 2017, 43, 4692-4701.

- Q. Li, Q. Zhang, H. Cui, L. Ding, Z. Wei, J. Zhai, Fabrication of cerium-doped lead dioxide anode with improved electrocatalytic activity and its application for removal of Rhodamine B, Chem. Eng. J., 2013, 228, 806–814.

- X. Zhao, Y. Zhu, Synergetic Degradation of Rhodamine B at a Porous ZnWO4 Film Electrode by Combined Electro-Oxidation and Photocatalysis, Environ. Sci. Technol., 2006, 40, 3367–3372.

- D.T.M. Thanh, P.T. Nam, N.T. Phuong, L.X. Que, N. Van Anh, T. Hoang, T.D. Lam, Controlling the electrodeposition, morphology and structure of hydroxyapatite coating on 316L stainless steel, Mater. Sci. Eng. C., 2013, 33, 2037–2045.

- H. Benhayoune, R. Drevet, J. Faur, S. Potiron, T. Gloriant, H. Oudadesse, D. Laurent-Maquin, Elaboration of monophasic and biphasic calcium phosphate coatings on Ti6Al4V substrate by pulsed electrodeposition current, Adv. Eng. Mater., 2010, 12, 192-199.

- S.D. Huelin, H.R. Baker, E.F. Merschrod S., K.M. Poduska, Phase-Selective Electroprecipitation of Calcium Phosphate Thin Films at Physiological Temperatures, Cryst. Growth Des., 2006, 6, 2634-2636.

- M.C. Kuo, S.K. Yen, The process of electrochemical deposited hydroxyapatite coatings on biomedical titanium at room temperature, Mater. Sci. Eng. C., 2002, 20, 153-160.

- A. Rakngarm, Y. Mutoh, Electrochemical depositions of calcium phosphate film on commercial pure titanium and Ti–6Al–4V in two types of electrolyte at room temperature, Mater. Sci. Eng. C., 2009, 29, 275-283.

- Y. Han, K. Xu, J. Lu, Morphology and composition of hydroxyapatite coatings prepared by hydrothermal treatment on electrodeposited brushite coatings, J. Mater. Sci. Mater. Med., 1999, 10, 243-248.

- A.K. Lynn, W. Bonfield, A Novel Method for the Simultaneous, Titrant-Free Control of pH and Calcium Phosphate Mass Yield, Acc. Chem. Res., 2005, 38, 202-207.

- N. Eliaz, M. Eliyahu, Electrochemical processes of nucleation and growth of hydroxyapatite on titanium supported by real-time electrochemical atomic force microscopy, J. Biomed. Mater. Res. Part A., 2007, 80, 621-634.

- C.A. Martinez-Huitle, S. Ferro, Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes, Chem. Soc. Rev., 2006, 35, 1324-1340.

- S. Song, J. Fan, Z. He, L. Zhan, Z. Liu, J. Chen, X. Xu, Electrochemical degradation of azo dye C.I. Reactive Red 195 by anodic oxidation on Ti/SnO2–Sb/PbO2 electrodes, Electrochim. Acta., 2010, 55, 3606-3613.

- G.F. Pereira, R.C. Rocha-Filho, N. Bocchi, S.R. Biaggio, Electrochemical degradation of bisphenol A using a flow reactor with a boron-doped diamond anode, Chem. Eng. J., 2012, 198-199, 282-288.

- M. Tertis, M. Jitaru, M. Toma, Electrochemical treatment of nitrophenols containing wastewaters, Sci. Study Res., 2008, IX, 281-292.

- T. Zeng, X. Yu, K. H. Ye, Z. Qiu, Y. Zhu, and Y. Zhang, BiPO4 film on ITO substrates for photoelectrocatalytic degradation, Inorg. Chem. Commun., 2015, 58, 39–42.


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